Name | 3,3',4,4'-Biphenyltetracarboxylic acid |
Synonyms | 3,3',4,4'-Biphenylte 4,4'-Biphthalic acid 5,5'-Bi[phthalic acid] 3,4,3',4'-Biphenyltetracarboxylic acid 3,3',4,4'-Biphenyltetracarboxylic acid Biphenyl-3,3',4,4'-tetracarboxylicacid 3,3',4,4'-[1,1'-Biphenyl]tetracarboxylic acid [1,1'-BIPHENYL]-3,3',4,4'-TETRACARBOXYLIC ACID |
CAS | 22803-05-0 |
InChI | InChI=1/C16H10O8/c17-13(18)9-3-1-7(5-11(9)15(21)22)8-2-4-10(14(19)20)12(6-8)16(23)24/h1-6H,(H,17,18)(H,19,20)(H,21,22)(H,23,24) |
Molecular Formula | C16H10O8 |
Molar Mass | 330.25 |
Density | 1.612g/cm3 |
Melting Point | >300 C |
Boling Point | 673.3°C at 760 mmHg |
Flash Point | 375°C |
Vapor Presure | 4.75E-19mmHg at 25°C |
pKa | 2.80±0.10(Predicted) |
Storage Condition | Sealed in dry,Room Temperature |
Refractive Index | 1.693 |
Use | Uses 3,3,4,4-biphenyltetracarboxylic acid is converted into 3,3,4,4-biphenyldianhydride after dehydration, which can be polymerized with a variety of diamine to obtain polyimide insulation material with excellent heat resistance, hydrolysis resistance, mechanical and flexibility. The material can be used for a long time below 333 ℃ and will not crack at -269 ℃. Biphenyl dianhydride polyimide has high mechanical strength, and the tensile strength of its polyimide film can reach 400MPa, and the change is very small with the increase of temperature. In addition, these materials also generally have good radiation resistance, excellent dielectric properties, stable chemical properties, strong creep resistance, excellent friction properties and other characteristics, have been widely used in aerospace, microelectronics and atomic energy and other high-tech fields. |
Hazard Symbols | Xi - Irritant |
Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin. |
Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36 - Wear suitable protective clothing. |
Raw Materials | 4,4'-Dimethylbiphenyl 4-BROMO PHTHALIC ANHYDRUS 3,3',4,4'-TETRAMETHYLBIPHENYL DIMETHYL 4-BROMOPHTHALATE Phthalic acid |
3,3,4,4, 4-biphenyltetracarboxylic acid is converted into 3,3,4,4, 4-biphenyldianhydride after dehydration. The latter can be polymerized with a variety of diamines to obtain excellent heat resistance and hydrolysis resistance. Polyimide insulation material with good mechanical and flexible properties. Polyimide synthesized from biphenyldianhydride and p-phenylenediamine has good temperature resistance, and its thermal decomposition temperature can reach above 600 ℃. It is one of the varieties with high thermal stability in polymers so far. At such a temperature, The original physical properties can be basically maintained in a short time.